The following works with SciTE version 1.66 (but probably applies to other versions too).
By default REBOL support is not activated, so to enable that (for example on linux, similar on windows):
Once you make all those changes you are able to see rebol color syntax for your beloved rebol scripts.
For ppl that want even better syntaxe colorization for SCITE
http://shadwolf.free.fr/SciTEGlobal.properties
http://shadwolf.free.fr/rebol.properties